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How it works?

When M&M’s are placed in water, the outer shell, which is made of sugar, dissolves. The sugar moves from a place of high concentration (the M&M) to a place of low concentration (the water away from the M&M). When the sugar shell dissolves and moves outward, it takes the layer of food dye with it. When more than one M&M is placed into a petri dish the colours do not mix because the concentration of sugar at the interface is approximately the same. 

Source: JMU Science